367737

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367737

Aldrich

 

Trimethyl(trifluoromethyl)silane solution

0.5 M in tetrahydrofuran

Synonym:(Trifluoromethyl)trimethylsilane
CAS Number:81290-20-2
Linear Formula:(CH3)3SiCF3
Molecular Weight:142.19
Beilstein Registry Number:4241868
MDL number:MFCD00145454
PubChem Substance ID:24862831

Details

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Description

ApplicationNucleophilic addition of the trifluoromethyl group to aldehydes and ketones.1
Packaging25 mL in Sure/Seal™
 5 mL in glass btl

Properties

vapor pressure10.98 psi ( 55 °C)
 2.8 psi ( 20 °C)
concentration0.5 M in tetrahydrofuran
bp40 °C
density0.895 g/mL at 25 °C

Safety

Hazard CodesF,Xn
Risk Statements11-19-22-36/37/38
Safety Statements16-26-36
RIDADRUN 1993 3/PG 2
Flash Point(F)-4 °F
Flash Point(C)-20 °C

References

Cited Reference1. J. Org. Chem. 71, 6806, (2006) Abstract
reference J. Am. Chem. Soc. 111, 393, (1989)
  J. Med. Chem. 35, 641, (1992) Abstract
  J. Org. Chem. 57, 1124, (1992)
FieserFieser 15,341
 Structure Index 1, 467:B:9